Since May last year, Mr. Gargan has been on suspension after claims surfaced of inappropriate advances made upon female colleagues.
The Police Chief has been found guilty of eight charges at a level of gross misconduct.
Police and Crime Commissioner Sue Mountstevens told reporters at a news conference that Mr. Gargan "abused his position by forwarding confidential emails, interfering with a proper recruitment process and sending, receiving and storing intimate images on his police issue phone."
She continues: "I believe that there is now a detrimental impact on the efficiency and effectiveness of him leading Avon and Somerset Constabulary, which is why I have today initiated the process to require him to resign."
Press Conference over Disgraced Police Chief Misconduct