The musician-and-TV star has designed the stunning new line for Littlewoods.com consisting of lacy red, black, and leopard prints sets, corsets and suspenders.
Myleene, 36 - who also models the line for the online retailer - says the collection is intended to make women feel "special" and with a price range starting at just £13, is described as "affordable luxury", reports The Mirror newspaper.
She said: "My collection is designed to provide affordable luxury for every woman - you deserve it.
"Your lingerie should make you feel really special.
"My favourite piece is the red lace underwear as the shade is in a sumptuous, hot hue, the strapping detail is hugely in trend and ultimately, it feels good to wear."
Meanwhile, the stunning brunette - who has two daughters Ava, six, and three-year-old Hero with her ex-husband Graham Quinn - recently opened up about her relationship with her new, unnamed, boyfriend, and revealed she has learnt to have fun again following the breakdown of her marriage in 2012.
She told Women's Health magazine: "I've learnt how to laugh and be fun and to not feel like just 'Mum' again.
"He taught me how to be me, because he had to learn who I was and he had no idea [I was famous].
"He doesn't work in the business. A girl's got to keep something to herself and ultimately you just want a nice guy."
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